Why I'm not writing a guide to buying CVVs
A CVV is the three- or four-digit code printed on a payment card, and it exists for one reason: to prove the person entering the card number is physically holding that card. There is no legitimate marketplace where CVV codes are sold as a product. When you see a "shop" offering them, what is actually being sold is stolen card data taken from breaches, skimmers, and phishing kits. Buying it is not a gray-area shortcut. In the US it falls under statutes covering access device fraud and identity theft, and the people running those sites are usually running a second scam on their own customers.
So I can't put together a buying guide, comparison of vendors, or checklist of "trusted" sites, because every version of that document is an instruction manual for a crime.
What I can help with instead
If your interest is on the defensive side, there's plenty of real work here. I can write about how card-not-present fraud is detected, why AVS and CVV checks are weighted differently by different processors, how chargeback ratios get merchants put into monitoring programs, or what PCI DSS actually requires of a small e-commerce shop. If you're a merchant trying to reduce fraud losses, or a writer covering payments, those are useful and legitimate topics.
If you found this because you were about to spend money on a card-data site, the honest advice is simpler than any guide: don't. You'll lose the money, you may hand your own identity to the operator, and you can end up facing charges rather than getting anything of value.